Maeno family
Kouki Maeno (前埜 光輝, Maeno Kōki)
Voiced by: Nobuyuki Hiyama (Japanese); Robert McCollum (English)
A young man with distorted memory whom Rin accidentally saves in episode one. He is, in fact, a clone created by Aoyama Pharmaceutical company. The original Koki Maeno died during an experiment that involved his vivisection. His memory lacks realism, as it is actually the memory of the original Koki written into the clone's brain by artificial means. After discovering the truth, he chooses to keep on living and starts working at Asougi Consulting, where he spends the next twenty-one years. Some time between episodes two and three, he marries Yuki Shimazaki and has a son named Teruki with her.
In episode three, he is shot by Sayara while rescuing Rin, and has to consume Shogo Shimazaki's time fruit in order to survive as an angel. After saving Rin and having one last tender moment with her, he returns to consume Sayara, but is killed (unlike that of immortals, the death of an angel is permanent regardless the time fruit) by Apos before he can finish. Koki's time fruit is lost in the sea but is inexplicably found by Rin while she regenerates in the ocean between episodes four and five. His granddaughter Mishio acquires it after Rin's body is destroyed in episode five, unwittingly brings it to Apos' castle in episode six, and passes it to Rin as the latter is consumed by Yggdrasil. Koki's spirit then helps Rin to break free.
Yuki Maeno (前埜 有紀, Maeno Yuki) née Shimazaki (島崎, Shimazaki)
Voiced by: Yoshino Takamori (Japanese); Cherami Leigh (English)
Koki's wife, whom he meets in episode two. During Koki's involvement in the case of her brother Shogo, the two grow fond of each other and marry some time between episodes two and three. In episode three, they have a son named Teruki. After Koki's death, Yuki continued to raise Teruki alone.
Shougo Shimazaki (島崎 省吾, Shimazaki Shōgo)
Voiced by: Hideo Ishikawa (Japanese); Ian Sinclair (English)
Yuki's older brother, who becomes an angel prior to episode two. Although most angels succumb to their primal desires quickly, Shogo's exceptional willpower allows him to retain consciousness for a very long time, which he uses to exact revenge upon people who previously maltreated him. After he finally loses his consciousness and attacks Rin, she has to kill him by impaling him with a tree branch. Apos expresses desire to obtain Shogo's time fruit but Rin instead gives it to Maeno, who eventually uses it to become an angel himself, saving Rin from Sayara. After Maeno is killed by Apos, his time fruit falls into the ocean and is lost until episode five.
Teruki Maeno (前埜 輝紀, Maeno Teruki)
Voiced by: Emiri Katō (Child), Daisuke Hirakawa (Adult) (Japanese); Brina Palencia (Young), Patrick W. Reid (Adult) (English)
Koki and Yuki's only son, who first appears as a child in episode three and becomes the male lead in episode four. Some time between episodes three and four, Rin saves his life in a car accident, and he states that he has felt watched over and protected by her ever since. Their formal introduction takes place in episode four, when Tamotsu brings him to Asougi Consulting due to his involvement in the Ruon case. He appears again in episode five, now the CEO of Maeno Holding Group company, with a teenage daughter named Mishio.
Mishio Maeno (前埜 美汐, Maeno Mishio)
Voiced by: Kaori Nazuka (Japanese); Luci Christian (English)
Teruki Maeno's only daughter and Koki's granddaughter, first appearing as a teenager in episode five. Finding Teruki's old video of Rin, she starts investigating her, frequently comparing herself to Sherlock Holmes. Upon the first meeting, they quickly grow fond of each other, and Mishio sticks with Rin and Mimi for the rest of the series. In episode six, Rin explains that Mishio is the youngest of Tajimamori's descendants.